The simulation results suggest that Cu is more acitve than other metals and water gas shift reaction is a structure sensitive reaction. 在此基础上,对该反应的结构敏感性进行了研究,发现该反应为一结构敏感反应,与实验结果相符。
In CO/ H2O system, the water gas shift reaction ( WGSR) produces high active H which can stab the residuals in order to improve the liquefaction conversion. 在CO/H2O系统中,发生的水煤气变换反应(WGSR)能产生高活性氢,该活泼氢能与煤热解产生的自由基结合生成稳定的液化产物,从而提高了液化的转化率。
Influence of Precipitation pH on Phase Composition of Catalyst ( CuO-ZnO/ Al_2O_3) Precursors and Activity of Catalyst in CO Water Gas Reaction 制备溶液pH对CuO-ZnO/Al2O3催化剂前体物相及其CO水汽变换反应活性的影响
Study of Structural Differences of LaMnO_ ( 3+ λ) on Water Gas Shift Reaction LaMnO(3+λ)的结构差异及对水汽转化反应活性的影响
The structure characteristics of the supported iron catalyst without chromium for water gas shift reaction 担载型无铬铁系水汽变换催化剂的结构特征
Intrinsic kinetics of water gas shift reaction over pt/ ceo_2-zro_2 Pt/CeO2-ZrO2催化剂上的CO变换反应本征动力学
A Study of Ti-Promoted Sulfur-Tolerant Co-Mo Catalyst for Water Gas Shift Reaction 钛促进的钴钼耐硫变换催化剂性能的研究
Effect of Mn, Co and Zr transitional metals on the catalytic properties of Cu_ ( 60)-Zn_ ( 30)-Al_ ( 10) catalyst for water gas shift reaction was studied. The samples were characterized by XRD, CO-TPD and H_2-TPR. 研究了锰、钴、锆等过渡金属对Cu60_Zn30_Al10变换催化剂性能的影响,并采用XRD、TPD、TPR等手段对其进行了表征。
The Adsorption-Desorption Study for the Low Temperature Water Gas Shift Reaction System by TPD 程序升温脱附法对低变反应体系的吸-脱附研究
The dehydrogenation of ethane was enhanced by CO2 because of the existence of the reverse water gas shift reaction and the Boudouard reaction. 由于存在逆水煤气反应和Boudouard反应,CO2能显著促进乙烷的脱氢反应。
DFT studies of activity of water gas shift reaction by several metals catalyzed 不同金属催化水煤气变换反应活性的DFT研究
The adsorption and water gas shift reaction mechanism on reduced cerium dioxide 二氧化铈还原表面上水煤气变换反应机理
The water gas shift reaction ( WGSR) is an important and elementary reaction in which hydrogen could be generated, and the hydrogen is necessary for hydrogenating desulfurization. 水气转换反应(WGSR)是一个重要基元反应,产生的氢可参与加氢脱硫作用;
Influence of Precipitation Temperature on Phase Composition of Precursor of CuO/ ZnO/ Al_2O_3 Catalyst and Its Catalytic Activity for Water Gas Shift Reaction 沉淀温度对CuO/ZnO/Al2O3催化剂前驱体物相及催化水煤气变换反应活性的影响
The experimental results showed that the water gas shift reaction could not reach thermodynamic equilibrium. 在内循环无梯度反应器内研究了C6H12-H2O转化反应的宏观动力学,实验结果表明,实验条件下,水-煤气变换反应并未达到平衡。
The mechanism of CO 2 oxidation is also discussed. It can be concluded that the remarkable promoting effect of CO 2 on the dehydrogenation of EB is due to both redox cycle of oxide catalyst and coupling of EB with reversed water gas shift reaction. CO2对乙苯脱氢的显著促进作用要归因于金属氧化物催化剂的氧化还原机制以及乙苯脱氢和逆水煤气变换反应耦合的协同作用。
Study of Fe/ AC Catalysts for the Coupling of Dehydrogenation of Ethylbenzene with Reversed Water Gas Shift Reaction 乙苯脱氢与逆水煤气变换偶合反应的铁/活性炭催化剂研究
Both the water gas shift reaction and the methanation reaction do not reach the thermodynamic equilibrium. 水煤气变换反应和甲烷化反应均未达到平衡;
The role of lattice oxygen and electron transport on iron-oxide-based catalyst systems was researched, which were based on investigations of activity for water gas shift reaction and the role of lattice oxygen in 11#, 210# ( Cr-free) and the literatures concerned. 在考察乙苯脱氢工业氧化铁系催化剂的中变(逆)活性和脱氧机理实验基础上,结合有关报道,探讨了氧化铁系催化剂晶格氧及电子传递作用。
Optimization operation of water gas shift reaction and promoting activity of organic sulfur hydrolysis reaction in order to removal organic sulfur. 优化变换工艺操作,促进有机硫水解反应的进行,从而脱除有机硫。
The results indicate that CO may capture a small amount of active sites on the catalyst surface which bring about the reverse water gas shift reaction. Thus the conversion of CO 2 is suppressed, but the selectivity to and yield of methanol are improved. 结果表明,CO占据了部分催化剂表面起逆水汽变换反应的活性位,从而降低CO2转化率,但甲醇选择性和收率得到了提高。
Effect of Potassium on Sulfur-Tolerant Catalyst for Water-Gas Shift Reaction 钾在水煤气耐硫变换催化剂中的作用
Studies on reduction performance of a catalyst for low temperature water gas shift reaction 低变催化剂还原性能研究
The Kinetic Study of Water Gas Shift Reaction and the Role of Reversible Adsorption& Monte Carlo Simulation 单晶表面上水-气转移反应动力学及可逆吸附的作用&MonteCarlo模拟研究
The reduction process of a CuO/ ZnO/ Al 2O 3 catalyst for low temperature water gas shift reaction was studied by XRD, TPR, etc. in a fixed bed reactor. 利用XRD、TPR和固定床反应装置对CuO/ZnO/Al2O3低变催化剂还原过程进行了深入考察。
Catalytic Performance of Pt/ CeO_2-ZrO_2 Monolithic Catalyst for Water Gas Shift Reaction Pt/CeO2-ZrO2整体催化剂上水汽变换反应催化性能的研究
Model discrimination and parameter estimation were performed for the kinetics models of Fischer-Tropsch synthesis ( FTS) and water gas shift reaction ( WGS) obtained in the previous paper on the basis of kinetic data measured by using a fixed bed reactor. 依据本文(Ⅰ)报获得的费托合成动力学模型及水煤气变换反应动力学模型,结合在固定床中测得的动力学数据,对几个候选动力学模型进行了参数回归。
The main content as follows: 1.Computational fluid dynamics ( CFD) methods used to simulate interior reaction of catalyst, a two-dimensional heterogeneous reaction model coupled with low-temperature water gas shift reaction is established. 主要内容如下:一、利用计算流体力学(CFD)方法模拟催化剂内部反应,建立了一个耦合低温水气变换反应的多孔介质二维拟均相反应器模型。
It is also found that increasing the space velocity favor methanation reaction, inhibit water gas conversion reaction. There was not obviously effect on space-time yield of liquid hydrocarbons. 此外,增加空速有利于甲烷化反应,抑制了水气转化反应,对液态烃类产率影响不大。
With the catalyst, the diesel fuel exhaust gas reforming reaction is endothermic, steam reforming reaction and water gas shift reaction are main reaction; partial oxidation reaction is secondary. 没有催化剂时,柴油废气重整反应是吸热反应,水蒸汽重整反应和水煤气反应是主要反应,氧化反应是次要反应。